Nomenclature of Carboxylic Group Preparation and Properties

Nomenclature of Carboxylic Group Preparation and Properties

→ Simple naming : Generally carboxylic acids are shown by their common or trivial name. The common name have been derived from latin or Greek names of their natural sources. The common name written in english end with the suffix ‘ic’ acid.

  • Formic acid (HCOOH) : It was first obtained from ants. In Latin the ants are termed as formica.
  • Acetic acid (CH3COOH) : ¡t was obtained from vinegar. In latin the vinegar is termed as acetum.
  • Butyric acid (CH3CH2CH2COOH) : It was obtained from rancid butter. In latin butter is termed as butyrum.
  • Veleric acid (C4H9COOH) : It was obtained from the roots of valenan plant hence it is called as veleric acid.
  • Propionic acid (C2H5COOH) : It is formed from protonpion word. In greek language the means of proton = first and pion = fat.

Nomenclature of Carboxylic Group Preparation and Properties

→ The position of the substituents in chain is indicated by the greek letters α, β, γ, δ etc. The carbon atom attach to —COOB group is called a carbon. Next to β, γ…………… etc.

Nomenclature of Carboxylic Group Preparation and Properties 1

→ IUPAC System : In IUPAC system aliphatic carboxylic acid are termed as alkanoic acid. The name of the acid is derived from the corresponding alkane by replacing the terminal e’ with oic acid’.

→ The longest chain containing the carboxylic group (—COOH) in the substituted carboxylic acid is selected. The carbon chain is numbered from the carboxylic acid group. The carbon of carboxyl group is always given the minimum number

→ Substituent are written as prefix with their numbering in aiphabatical order before main alkane. Suffic oic acid’ is used in end.

Example:

Nomenclature of Carboxylic Group Preparation and Properties 2

→ In naming of compound containing more than one carboxylic group the last letter ‘e’ of the english name of the alkane remains as it is. The number of carboxylic group are indicated by adding the multiplication prefix di, tri etc before the word carboxylic acid.

Nomenclature of Carboxylic Group Preparation and Properties

Common and IUPAC name of some Carboxylic Acid

Nomenclature of Carboxylic Group Preparation and Properties 3 Nomenclature of Carboxylic Group Preparation and Properties 4

→ Nomenclature of Poly carboxylic acid : Following rules are used for their nomenclature

→ If two —COOH group are present then both carbon are counted in main carbon chain.

Nomenclature of Carboxylic Group Preparation and Properties 5

→ if three or more than three —COOH group are present then all of them are lefted in carbon chain and instead of ‘oie acid’ suffix ‘carboxylic acid’ is used in its place.

Nomenclature of Carboxylic Group Preparation and Properties 6

Chemistry Notes