Nomenclature of Alcohols Preparation and Properties

Nomenclature of Alcohols Preparation and Properties

Nomenclature of Alcohols :

Here we will discuss three systems of nomenclature.

→ Common System : According to this system alcohols are called as a1kyl alcohols’.

For example:

Nomenclature of Alcohols Preparation and Properties 1

→ Carbinol System : In this sytem, the simplest monohydric alcohol. CH3OH is called carbmol while other alcohols are named as alkyl derivatives of carbinol.

For example:

Nomenclature of Alcohols Preparation and Properties 2

→ IUPAC System : In IUPAC Nomenclature system, alcohols are named by replacing ‘e’ in the name of parent alkane by ‘ol’.

Alkane – e + ol = Alkanol

Therefore, alcohols are known as ‘alkanol’ in IUPAC system. Following steps are followed in this system:

→ The longest chain containing the carbon bonded to — OH group is selected as the parent chain.
The carbon atoms in the chain are numbered in such a way so that the carbon atom carrying the hydroxyl group gets th lowest number. In the parent chain, if substituents other than the main functional group —OH are present, they are written in prefix according to alphabetical order.

Nomenclature of Alcohols Preparation and Properties

→ The name of an alcohol is derived from the name of the alkane (according to total number of carbon atoms present in parent chain) from which the alcohol is derived, by substituting ‘e’ of alkane with the suffix ‘ol’.

→ If more than one —OH groups are present in an organic compound, the number of—OH groups is indicated by adding the multiplicative prefix such as di, tri, tetra etc., before ‘ol’.

→ The positions of —OH groups are indicated by appropriate locants e.g., HO—CH2—CH2—OH. It’s IUPAC name is ethane.1, 2-diol.

Examples:

Nomenclature of Alcohols Preparation and Properties 3 Nomenclature of Alcohols Preparation and Properties 4

Table 11.1 Common and IUPAC names of few alcohols:

Nomenclature of Alcohols Preparation and Properties 5 Nomenclature of Alcohols Preparation and Properties 6

Chemistry Notes